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The day before cooking the pork... Add hot water to a large pot - I use an 8 quart pasta pot.
Mix up the rub and apply an even coating of the rub all around the pork shoulder. You will have excess rub.
Add 2-3 cups of hot water to the pan. Enough to have 0.5 to 1 inch of water, but not so much the vegetables are floating around.
Add or reduce time depending on the size of the Pork Shoulder. I would plan on 30-45 min for each pound. When fall off the bone tender, the internal temperature should reach around 200 F. Check with a fork for tenderness.